Journal
CRYSTENGCOMM
Volume 12, Issue 12, Pages 4045-4047Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ce00178c
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [20036040]
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A one-dimensional homochiral (MoCuII)-Cu-IV compound, [Cu(tren)]-[ Cu(33)][Mo(CN)(8)]center dot 4H(2)O (1, tren = tris(2-aminoethyl) amine, 33 = bis(3-aminopropyl)amine), was synthesized and characterized. Compound 1 experiences spontaneous resolution from achiral components and crystallized in a chiral space group P2(1). It exhibits photomagnetism via photoinduced metal-to-metal charge transfer, making it a novel example of multifunctional molecule-based materials.
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