Journal
CRYSTENGCOMM
Volume 12, Issue 2, Pages 337-340Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b917264p
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Funding
- NSF of China [20701025, 20601025]
- Natural Science Foundation of Shandong Province, Shandong University [Y2008B01]
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Two 1D coordination polymers with a 1D zigzag and a helical chain, respectively, have been solvothermally synthesized. The different coordinated small molecules on the cadmium ion have significant influences on the formation of different architectures. Due to the existence of supramolecular interactions between the helices in complex 2, the same chirality is preserved, resulting in a chiral architecture. By introducing a chiral molecule as cosolute, the bulk homochiral crystallization from achiral precursors for 2 can be achieved.
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