4.7 Article

Organic hydrogen-bonded interpenetrating diamondoid frameworks from modular self-assembly of methanetetrabenzoic acid with linkers

Journal

CRYSTENGCOMM
Volume 11, Issue 6, Pages 978-979

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b822936h

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Funding

  1. National Natural Science Foundation of China [20672118]
  2. Major State Basic Research Development Program of China [2007CB8008005]
  3. Chinese Academy of Sciences [KJCX2-YW-H13]

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The modular self-assembly of methanetetrabenzoic acid with similar linear linkers, phenazine and 4,4'-bipyridine, affords two different interpenetrating diamondoid frameworks which show a normal 7-fold mode of interpenetration (class Ia), and an unusual 18-fold interpenetration (class IIIb, [3 x 3 x 2]), respectively.

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