Journal
CRYSTENGCOMM
Volume 11, Issue 11, Pages 2268-2271Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b910263a
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Funding
- Beijing Natural Science Foundation [2082007]
- Project for Science and Technology Development
- Beijing Commission of Education [KM200810025026]
- NSFC [20771009]
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A simple anthryl derivative 1-((anthracen-10-yl)methylene)-4-ethyl-thiosemicarbazide (ANS) shows a methanol-tunable solid state fluorescence enhancement based on different molecular packing structure; the emission is stronger in crystal 2 than that in crystal 1 under the same condition. This is mainly due to the formation of face-to-face pi center dot center dot center dot pi stacking assembly in crystal 2 which is directed and enhanced by intermolecular H-bonding interactions. The observation of fluorescence decay corroborates the formation of an emissive excimer in the pi center dot center dot center dot pi stacking assembly.
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