Journal
CRYSTENGCOMM
Volume 11, Issue 8, Pages 1615-1620Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b902121c
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Funding
- National Natural Science Foundation of China [20701041, 20701037]
- Natural Science Foundation of Chongqing [CSTC2007BB4234]
- Scientific Project of Chongqing Municipal Education Commission [KJ070812]
- Major Scientific Foundation of Chongqing Normal University [08XLZ09]
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Using cyanide anions and sulfur simple substance as precursors of thiocyanate groups, three desired luminescent halogeno-thiocyano-d(10) metal complexes, namely, [Me4N][Cu(SCN)Br] (1) with a 1-D to 2-D architecture constructed through C-H center dot center dot center dot Br hydrogen bonds, [Me4N][Cu(SCN)I] (2) with a 1-D to 3-D framework constructed through C-H center dot center dot center dot I hydrogen bonds, and [Me4N][Ag-2(SCN)(2)Cl] (3) with a special 3-D nanoporous structure constructed by mu-chloride atoms connecting the 2-D neutral N-2[Ag-2(SCN)(2)] layers, have been solvothermally synthesized and all exhibit efficient luminescence. The luminescent behavior of the three complexes was illustrated through the density functional theory.
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