Journal
CRYSTENGCOMM
Volume 10, Issue 11, Pages 1687-1692Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b815423f
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Funding
- European Union
- EPSRC [EP/C51194]
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The first examples of anionic-neutral mixed ligand frameworks prepared from 1,3, 5-benzenetrisbenzoate (BTB) and 4,4 '-bipyridyl (bipy) are reported. Framework 1, of composition [Ni(HBTB)(bipy)]center dot(guests), is a triply interpenetrated (3,5)-connected gra binodal network that has a 1-D channel structure exhibiting permanent porosity. Framework 2, which was prepared under identical conditions but in the presence of toluene, has the formula [Ni-3(BTB)(2)(EG)(3)(bipy)(3)]center dot(toluene) (where EG ethylene glycol). 2 is a dense phase of triply interpenetrated rare (3,4)-connected tfz binodal networks that contains intercalated toluene in isolated voids. The primary influence for the formation of 2 are numerous hydrophobic interactions between the internal framework surface and the included toluene guest molecule.
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