Journal
CRYSTENGCOMM
Volume 10, Issue 11, Pages 1501-1515Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b812026a
Keywords
-
Categories
Funding
- Graduate Research School Combination Catalysis''
- NIOK
- HRSMC
- PTN COST program Action [D35/0011]
- FP6 Network of Excellence Magmanet'' [515767]
Ask authors/readers for more resources
Anion - pi interactions have been receiving a great deal of attention from the scientific community for the past five years. This type of non-covalent bond is being recognized as a supramolecular interaction by chemists. Remarkably, the status for the lone pair(lp)-pi interaction, namely the bonding association between a neutral electron-rich molecule and an electron-poor p ring, is hardly studied. The importance of lp-pi interactions was clearly evidenced in a number of biological systems more than ten years ago; amazingly, only a few examples of lp-pi interactions involving small synthetic molecules have been reported so far in the literature. Are these examples unique? Actually, a detailed analysis of the Cambridge Structure Database shows that such interactions are not unusual in organic compounds, but apparently have been overlooked in the past.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available