Journal
CRYSTENGCOMM
Volume 10, Issue 11, Pages 1662-1666Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b812782b
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Funding
- Natural Science Foundation of China [20671041, 20701015]
- State Key Laboratory of Inorganic Synthesis
- Preparative Chemistry of Jilin University
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Two new metal-organic frameworks [Cd-3(H2O)(2)(C5N2O4H)(2)center dot H2O] 1 and [KCd(C7N2O4H5)] 2 have been hydrothermally synthesized employing 4,5-imidazoledicarboxylic acid (IMDC) and 2-ethyl-4,5-imidazoledicarboxylic acid (2-EtIMDC) as organic ligands. The single-crystal structure analysis reveals that compound 1 exhibits a 3-D framework, which is generated from 2-D layers pillared by 1-D chains along the c-axis. Compound 2 presents a 3-D structure with 1-D channels, which are connected in a cross-like fashion by [CdN2O3] trigonal bipyramid units and 2-EtIMDC ligands.
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