Journal
CRYSTENGCOMM
Volume 10, Issue 9, Pages 1211-1215Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b718995h
Keywords
-
Categories
Ask authors/readers for more resources
By tuning the ratio of solvents in a binary solvent mixture, the coordination geometries of the metal centers were controlled and three 2Dcoordination polymers, [Zn(bdc)(dma)](n)1, [Zn(3)(bdc)(3)(dma)(2)](n)2 and {[Zn(bdc)(H(2)O)]center dot(DMA)}(n)3, were synthesized from zinc(II) nitrate and H(2)bdc in water/DMA solvents (H(2)bdc benzene-1,4-dicarboxylic acid, DMA N, N-dimethylacetamide). As the ratio of water/DMA increases, the number of DMA ancillary ligands coordinated to the zinc ion decreases, until all the DMA are substituted by water. The change in the ratio of solvents ( which also act as ancillary ligands) affords a means to adjust the local coordination environment of the zinc ion, leading to three types of SBUs, which further determine the topologies and the packing modes of the coordination polymers.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available