Journal
CRYSTENGCOMM
Volume 10, Issue 10, Pages 1379-1383Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b805263h
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Funding
- National Nature Science Foundation of China [20771056]
- National Basic Research program of China [2007CB925102]
- State Basic Research Project of China [20490218]
- Jiangsu Science & Technology Department
- Center of Analysis and Determining of Nanjing University
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Two new metal-organic complexes [Cd-1.5(btrc)(bix)](n) (1) and [Zn-2(btrc)(Hbtrc)(0.5)(bix)(2)](n)(2) (H(3)btrc = 1,2,4-benzenetricarboxylate; bix = 1,4-bis(imidazol-l-ylmethyl)-benzene) have been hydrothermally synthesized and characterized by single crystal X-ray diffraction. Complex 1 represents a three-dimensional (3D) structure based on the 2D sheets and bix pillars. Complex 2 exhibits unique architecture. The two complexes exhibit strong fluorescent emissions in their solid states at room temperature.
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