Journal
CRYSTENGCOMM
Volume 10, Issue 8, Pages 1070-1073Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b802226g
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The hydrothermal reaction of In(III) and pyridine-3,5-dicarboxylic acid in the presence of triethylamine leads to a generation of novel 3D homochiral coordination polymers with In-OH-In helical chains. Interestingly, the resulting crystals were not a racemic mixture but had an enantiomeric excess, which was confirmed by the measurement of optical rotation of bulk samples using solid state vibrational circular dichroism (VCD) spectra.
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