Journal
CRYSTAL RESEARCH AND TECHNOLOGY
Volume 43, Issue 4, Pages 350-354Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/crat.200711106
Keywords
DSC; thermal analysis; phase diagram; lithium molybdates
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The quasi-binary phase diagram lithium oxide - molybdenum(VI) oxide was investigated by differential scanning calorimetry and X-ray diffraction. The four intermediate phases Li4MoO5, Li2MoO4, Li4Mo5O17, and Li2Mo4O13 show incongruent melting. The system has one eutectic point at 50.5 mol% MoO3 and 49.5 mol% LiO0.5 with a eutectic temperature of 524.6 degrees C. At this point the melt is in equilibrium with Li2MoO4 and Li4Mo5O17. (C) 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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