Journal
CRYSTAL GROWTH & DESIGN
Volume 14, Issue 12, Pages 6472-6477Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg501332u
Keywords
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Funding
- Korea CCS R&D Center (KCRC) - Korea government (The Ministry of Science, ICT & Future Planning (MSIP)) [NRF-2014M1A8A1049253]
- Basic Science Research Program [NRF-2012R1A1A2007141]
- Priority Research Centers Program [NRF20100020209]
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Two porous metalorganic frameworks [Co(Tt)(2)][Cu-4(D-cam)(4)]center dot 5H(2)O center dot DMF (1; Tt = tris(triazolyl)borate, D-H(2)cam = D-(+)-camphoric acid or (1R,3S)-1,2,2-trimethyl-1,3-cyclopentanedicarboxylic acid) and [Co(Tt)(2)][Cu-4(L-cam)(4)]center dot 5H(2)O center dot 2DMF (2; L-H(2)cam = l-(-)-camphoric acid or (1S,3R)-1,2,2-trimethyl-1,3-cyclopentanedicarboxylic acid) were prepared by mixing Cu2+, Co(Tt), and camphoric acid under solvothermal conditions. The structures of 1 and 2 reveal that the two-dimensional layers composed of chiral ligands and Cu-Cu paddlewheel units are connected through the metalloligands to form three-dimensional networks. It is noted that these solids show multifunctional properties such as gas adsorption onto the pores of the frameworks, antiferromagnetic coupling between spin carriers, and a small enantioselective separation of racemic alcohols.
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