Journal
CRYSTAL GROWTH & DESIGN
Volume 14, Issue 5, Pages 2522-2526Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg500235j
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Funding
- Welch Foundation [AX-1730]
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A new organic ligand of pyrene-containing tetracarboxylic acid and its first metal organic framework UTSA-72 was designed and synthesized. The MOF has the two-dimensional (4,4) framework topology. The activated UTSA-72a exhibits permanent porosity and moderately high selectivities for CO2/N-2, C2H2/CH4, and CO2/CH4 gas separations at room temperature because of the small pores within the framework.
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