Journal
CRYSTAL GROWTH & DESIGN
Volume 14, Issue 6, Pages 2753-2762Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg401891f
Keywords
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Funding
- IRCSET [PD/2012/2652, EPSPG/2011/146]
- Bruker UK
- Science Foundation Ireland [12/RC/2275, 05/PICA/B802/EC07]
- UCC Strategic Research Fund
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The crystal landscape of a series of primary aromatic thioamides is described, displaying similar characteristic intermolecular hydrogen-bonding interactions in the solid state to those observed in their widely studied amide analogues, including R-2(2)(8) dimers and C(4) chains. In a number of cases, high Z' values were observed in the structures. On the basis of the observed solid-state features, the thioamide functional group, which is a strong hydrogen-bond donor and moderate acceptor, offers considerable potential as a key moiety for crystal engineering.
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