Journal
CRYSTAL GROWTH & DESIGN
Volume 13, Issue 5, Pages 2094-2097Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg400164m
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Funding
- National Natural Science Foundation of China [51272231, 51229201, 51010002]
- Welch Foundation [AX-1730]
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To immobilize open Cu2+ sites and tube suitable pore spaces, we have realized a doubly interpenetrated metal-organic framework (MOF) [Cu2L-(H2O)(2)]center dot(DMF)(6)center dot H2O (ZJU-30, ZJU = Zhejiang University; H4L = biphenyl-3,3',5,5'-tetra-(phenyl-4-carboxylic) acid; DMF = N,N-dimethylformamide) for the highly selective separation of C-2 hydrocarbons over C-1 methane with the Henry law's selectivities from 9.58 to 29.8 in the temperature range from 273 to 298 K.
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