Journal
CRYSTAL GROWTH & DESIGN
Volume 12, Issue 2, Pages 970-974Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg201444p
Keywords
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Funding
- National Nature Science Foundation of China [21161002]
- Key laboratory of new processing technology for nonferrous metals and materials, Ministry of Education, Guangxi University [GXKFZ-02]
- Guangxi Natural Scientific Foundation of China [0991108, 0832111]
- Guangxi Science and Technology Agency Research Item of China [0895002-9]
- Robert A. Welch Foundation of the University of Texas at Austin [F-816]
- National Science Foundation, USA [CHE-0741973]
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Four hexanuclear lanthanide salen complexes [Ln(6)(L-1)(4)(OH)(4)(MeOH)(4)]center dot 2Cl center dot 4MeOH (Ln = Nd (1), Th (2)), [Eu-6(L-2)(4)(OH)(4)(MeOH)(2)(EtOH)(2)(H2O)(2)]center dot 2Cl center dot 3EtOH center dot H2O (3), and [Er-6(L-2)(4)(OH)(4)(EtOH)(2)(H2O)(2)]center dot 2Cl center dot 2EtOH center dot MeOH center dot H2O (4) are formed from the reactions of LnCl(3)center dot 6H(2)O and flexible Schiff base ligands H2L1 and H2L2 (H2L1 = N,N'-bis(3-methoxysalicylidene)(propylene-2-ol)-1,3-diamine, H2L2 = N,N'-bis(salicylidene)(propylene-2-ol)-1,3-diamine). The structures of 1-4 were determined by single crystal X-ray crystallographic studies, 800 1000 1200 and their luminescence properties were determined.
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