Journal
CRYSTAL GROWTH & DESIGN
Volume 12, Issue 2, Pages 854-861Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg201244y
Keywords
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Funding
- Fonds der Chemischen Industrie
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Four homoleptic coordination polymers of general composition [Ag(4ABN)(4/2)]X (4ABN equivalent to 4-aminobenzonitrile) were synthesized and characterized by X-ray single crystal structure analysis. For X = NO3- (P2(1)/n, Z = 4; 1), PF6- (P2(1)/n, Z =4; 2), and ClO4- (P2(1)/n, Z = 4; 3), similar topologies with undulated layers (6(3) nets) are found, which are separated by the anions. For X = SO3CF3- ((1) over barP, Z = 2; 4), a one-dimensional structural fragment with polymeric double-bridged cationic chains again separated by the anions is formed. It is rationalized that different dimensionalities of the polymeric structural fragments depend upon the size of the separating counteranions. This simple rule can also be applied for already known infinity(2)[Ag(4ABN)(4/2)]BF4.
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