Journal
CRYSTAL GROWTH & DESIGN
Volume 12, Issue 3, Pages 1064-1068Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg2014495
Keywords
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Funding
- National Science Foundation of China [21031002, 51073079]
- 973 Program of China [2012CB821700]
- Natural Science Fund of Tianjin, China [10JCZDJC22100]
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An unusual 3D 10-connected metal-organic framework [Zn-5(mu(3)-OH)(2)(1,4-ndc)(4)(1,4-bix)(2)] (1, 1,4-ndc = 1,4-naphthalenedicarboxylic acid; 1,4-bix = 1,4-bis(imidazol-1-ylmethyl)benzene) has been hydrothermally synthesized and structurally characterized. Topological analysis indicates that 1 is a 3D 10-connected self-penetrating framework based on [Zn-5(mu(3)-OH)(2)] pentanuclear zinc clusters as secondary building units with the short Schlafli symbol of 3(6)4(34)5(3)6(2). This represents highly connected a uninodal network topology presently known for self-penetrating systems. Moreover, the TGA and luminescence properties of 1 were investigated.
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