Journal
CRYSTAL GROWTH & DESIGN
Volume 12, Issue 10, Pages 4798-4804Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg300587b
Keywords
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Funding
- Graduate Study Councils of Shahid Beheshti University
- General Campus
- Iran National Science Foundation [87041984]
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Two coordination polymers [Hg2Cl4L center dot 2-(DMF)](n), 1, and [Hg2Br4L center dot 2(DMF)](n), 2, where L is the N,N'-(1,2-diphenylethane-1,2-diyl)diisonicotinamide ligand, have been synthesized and characterized. X-ray single crystal diffraction reveals that both coordination polymers are isostructural and that mercury adopts square based pyramid coordination geometry. Our results show that interplay between the coordination of the carbonyl group and pi...pi It interaction of adjacent pyridine rings leads to the formation of 2D structures.
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