Journal
CRYSTAL GROWTH & DESIGN
Volume 11, Issue 6, Pages 2243-2249Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg101610k
Keywords
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Funding
- National Natural Science Foundation of China [20771008, 20821091]
- National Key Basic Research Project of China [2010CB833103]
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Three new compounds, [ZnNa(BTC)(H2O)(2)]center dot H2O (1), [Zn3Na2(BTC)(2)(HCOO)(2)(H2O)(8)] (2), and [Zn3Na(BTC)(2) (HCOO)(H2O)3]center dot H2O (3) (H3BTC = 1,3,5-benzenetricarboxylate acid), were synthesized under hydrothermal conditions and were characterized by the single crystal and powder X-ray diffraction, IR spectra, elemental analyses, ICP measurements, and coupled TG-MS analyses. 1, 2, and 3 crystallize in the space groups P (1) over bar, C2/c, and P1, respectively. They are three-dimensional (3D) frameworks, consisting of zigzag chains ((Na2Zn2O14)(n) for 1, (Na2Zn3O18)(n) for 2, or (NaZn3O14)(n) for 3) and bridging BTC ligands. Powder X-ray diffraction studies reveal that 1 and 2 exhibit reversible dehydration-rehydration behaviors with a crystal-to-crystal transformation observed for 2.
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