Journal
CRYSTAL GROWTH & DESIGN
Volume 11, Issue 9, Pages 3707-3712Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg2005776
Keywords
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Funding
- National Natural Science Foundation of China [51071116, 50871080, 50901056]
- National Basic Research Program of China [2010CB635101]
- DOE [DE-FG02-03ER46028]
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We have developed a periodic nucleation and growth mechanism for nanopartide-aggregated structure based on electron tunneling process that occurs in chemical replacement reactions. This electron tunneling process, which is a fundamental physical phenomenon, successfully explains the repeated formation of nanoparticles that has been observed in the experiment. Using the nanopartic.le-mediated progress, we have interpreted the origin of layer-by-layer nanoparticle stacking polycrystalline nanostructures and mesocrystal in chemical reductions.
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