Journal
CRYSTAL GROWTH & DESIGN
Volume 11, Issue 9, Pages 3713-3716Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg200579j
Keywords
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Funding
- Department of Energy-Basic Energy Sciences [DE-SC0002235]
- NSF [DMR-0846958]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [0846958] Funding Source: National Science Foundation
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A nine-connected metal organic framework [Ni(2)(II)Ni(III)-(mu(3)-OH)(IN)(3) (BDC)(1.5)]center dot xSolvent (BDC = benzene-1,4-dicarboxylate, IN = isonicotinate) has been prepared and characterized. The application of the scale-down chemistry through the use of the short and inexpensive BDC and IN ligands leads to a smaller pore size and lower surface area but little compromise in H(2) sorption properties. The compound exhibits a high CO(2) uptake of 73.1 cm(3) g(-1) (273 K and 1 atm) despite its moderate Langmuir and BET surface areas (888.3 and 571.0 m(2) g(-1), respectively). Its H(2) uptake (1.47 wt % at 77K and 1 atm) is also quite high, comparable to that of many materials with high surface area.
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