Journal
CRYSTAL GROWTH & DESIGN
Volume 11, Issue 12, Pages 5696-5701Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg201226t
Keywords
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Funding
- NSFC [91027003, 21072118]
- PCSIRT
- 973 Program [2012CB821705]
- Shangdong Natural Science Foundation [JQ200803]
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A new Cd(II)-MOF (1) was successfully synthesized on the basis of a new long double Schiff-base ligand and Cd(SCN)(2). Its crystal structure was determined by X-ray diffraction. In 1, each pair of Cd(II) nodes is bridged by two inversely related mu-SCN- to form infinite inorganic chains with the remaining two trans-positions being occupied by two Schiffbase figands to generate a 3D framework with rhombus-like channel (similar to 9 x 9 angstrom). 1 can reversibly absorb CH2Cl2 and CHCl3 at different temperature without collapsing of the host framework. Furthermore, it displays a strict size selectivity and can completely separate these volatile chlorocarbons of CH2Cl2 and CHCl3 in liquid and vapor phases.
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