Journal
CRYSTAL GROWTH & DESIGN
Volume 10, Issue 10, Pages 4537-4541Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg1008347
Keywords
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Funding
- Collaborative Research Consortium of Nanocrystal Ceramics
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Monodispersed CeO2 nanocubes were prepared by using a liquid-liquid interface. The morphology of CeO2 nanocrystals from the aqueous phase changed from truncated octahedron to nanocube in the toluene phase at the water-toluene interface. The CeO2 nanocubes oriented to form large cubic particles at a low molar ratio of oleic acid (OLA)/Ce. The red-shift of the absorption edge and the high concentration or Ce3+ in the CeO2 structure was identified for the CeO2 nanocrystals. The high concentration of Ce3+ in the CeO2 structure was identified as one of the main reasons for the red-shift of the absorption edge of CeO2 nanocrystals.
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