4.7 Article

A New Multidentate Hexacarboxylic Acid for the Construction of Porous Metal-Organic Frameworks of Diverse Structures and Porosities

Journal

CRYSTAL GROWTH & DESIGN
Volume 10, Issue 6, Pages 2775-2779

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/cg100316s

Keywords

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Funding

  1. NSF [CHE 0718281]
  2. National Science Foundation/Department of Energy [NSF/CHE-0822838]
  3. U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
  4. NSF of China
  5. Direct For Mathematical & Physical Scien
  6. Division Of Chemistry [0822838] Funding Source: National Science Foundation

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Three porous metal organic frameworks have been constructed from the new developed C3-symmetric hexacarboxylic acid 3,3',3 '',5,5',5 ''-benzene-1,3,5-triyl-hexabenzoic acid (H(6)BHB) of different NaCl- and Al(2)O(3)-type topologies. The activated metal-organic frameworks (MOFs) exhibit permanent porosities as revealed in their gas and vapor adsorption isotherms, highlighting the promise of this new ligand for the construction of porous MOFs for gas storage and separation.

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