4.7 Article

Coaxial Core Shell Overgrowth of Zeolite L - Dependence on Original Crystal Growth Mechanism

Journal

CRYSTAL GROWTH & DESIGN
Volume 10, Issue 12, Pages 5182-5186

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/cg100964j

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Funding

  1. EPSRC
  2. ExxonMobil Research and Engineering
  3. Knut and Alice Wallenberg Foundation

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In this study, the first reported core-shell material combining zeolite L (LTL) and barium-exchanged zeolite L (Ba-LTL) is described The use of atomic force microscopy to probe the LTL surface growth mechanism was employed to understand the growth pattern of the resultant Ba-LTL coaxial overgrowth layer Additionally the dependence of the original crystal surface on the resulting habit of the Ba-LTL core-shell layer is explained High-resolution scanning electron microscopy (HRSEM) was employed to observe the fine detail of the Ba-LTL layer, and cross-sectional polishing was used to view the boundary between the two crystalline materials

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