4.7 Article

Generation of 2D and 3D (PtS, Adamantanoid) Nets with a Flexible Tetrahedral Building Block

Journal

CRYSTAL GROWTH & DESIGN
Volume 10, Issue 9, Pages 3843-3846

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/cg1005677

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Funding

  1. U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering [KC020105-FWP12152]
  2. U.S. Department of Energy [DE-AC05-76RL01830]

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The self-assembly of the flexible tetrahedral linker tetrakis[4-(carboxyphenyl)oxamethyl]methane acid with various transition metals (Cu, Co, and Mg) results in a 2D layered structure and 3D frameworks with PtS and adamantanoid topology. The PtS net exhibits permanent porosity, as confirmed by BET and gas adsorption experiments.

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