Journal
CRYSTAL GROWTH & DESIGN
Volume 10, Issue 6, Pages 2571-2580Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg9015383
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Funding
- Science Foundation Ireland [05PICAI819]
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The present study focuses on understanding hydrogen bond patterns in a series of variably substituted pyridyl-pyridazines as a function of positional isomerism and steric factors. A relatively uncommon multiple hydrogen bond acceptor nature of pyridazine has been observed in the di- and tripyridazinc compounds. With increasing aromatic substitution and thereby steric hindrance, a systematic transition has been observed from close-packed to porous solvated assemblies. Distinct morphologies of the organic nano/microparticles, obtained by the precipitation method, indicate that the molecules interact with the solvent system in different ways.
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