Journal
CRYSTAL GROWTH & DESIGN
Volume 9, Issue 7, Pages 3327-3332Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg900220g
Keywords
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Funding
- Nebraska EPSCoR
- Nebraska Center for Energy Sciences Research
- Nebraska Center for Materials and Nanoscience
- University of Nebraska-Lincoln
- Research Council
- UCARE program at University of Nebraska-Lincoln.
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A new series of porphyrin paddlewheel frameworks (PPFs) has been assembled from 5,10,15,20-tetrakis(4-carboxyl)-21H,23H-porphine (TCPP), Zn(NO3)(2)center dot 6H(2)O, and organic pillars such as N,N'-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNI) and 3,6-di-4-pyridyl-1,2,4,5-tetrazine (DPT). Here we report the synthesis and structural characterization of five new PPFs based on 2D porphyrin paddlewheel grid. In this homologous series, the stacking patterns of such 2D porphyrin sheets are varied and exhibit two new structures, namely, bilayer and interpenetrated AA stacking pattern, in addition to the ABBA pattern previously observed.
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