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Highly Tunable Heterometallic Frameworks Constructed from Paddle-Wheel Units and Metalloporphyrins

Journal

CRYSTAL GROWTH & DESIGN
Volume 9, Issue 4, Pages 1960-1965

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/cg801267m

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Funding

  1. Nebraska EPSCoR

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Seven new heterometallic frameworks have been synthesized with specific control over the metallic composition of each structure. Using Mn, Fe, Ni, V, and Pt metallated tetra-(4-carboxyphenyl)porphine (MTCPP) metalloligands and Zn and Co paddle-wheel building units, two series of heterometallic frameworks are assembled that maintain topology with changing metal composition.

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