Journal
CRYSTAL GROWTH & DESIGN
Volume 9, Issue 11, Pages 4588-4591Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg900735n
Keywords
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Funding
- NAVAIR ILTR program
- N*Star program (Naval S&T for America's Readiness)
- DTRA
- U.S. Dept. of Energy
- Northwestern NSEC
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The occluded solvent in a mixed ligand metal-organic framework has been displaced by n-hexanol, chloroform, and nitrobenzene in a crystal to crystal guest exchange. The X-ray structures of the three new solvent addticts of Zn(2)NDC(2)DPNI(2) reveal the complete replacement of N',N-dimethylformamide with the new guest. Structural changes to the framework geometry in response to the size of the incoming guest are also exhibited. These new frameworks are characterized by powder X-ray diffraction, thermal gravimetric analysis coupled with infrared spectroscopy, and cross-polarization magic angle spinning NMR.
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