4.7 Article

Facile production of self-assembly hierarchical dumbbell-like CoOOH nanostructures and their room-temperature CO-gas-sensing properties

Journal

CRYSTAL GROWTH & DESIGN
Volume 8, Issue 10, Pages 3497-3500

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/cg8002367

Keywords

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Funding

  1. National Natural Science Foundation of China [20671003]
  2. Natural Science of Anhui Education Committee [2006kj041a]
  3. Young Teacher Sustentation Project of Anhui [2005jq1041zd]
  4. Education Department of Anhui Province [2006KJ006TD]

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In this paper, we report a simple and novel coordination compound precursor route to synthesize the hierarchical dumbbell-like CoOOH nanostructures in high yield. A possible growth mechanism governing the formation of such nanostructures is discussed. The CO-gas-sensing properties of the as-synthesized nanostructures are investigated in detail. The dumbbell-like CoOOH nanostructures have a large active surface area of {110} facets, which can provide sufficient space for the interaction between CoOOH and the detected gases. As a result, the as-prepared dumbbell-like CoOOH nanostructures exhibit a superior sensitivity to CO at room temperature, as well as good reproducibility and short response/recovery times. The as-prepared CoOOH nanostructures could have potential applications in nanosensors.

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