Journal
CRYSTAL GROWTH & DESIGN
Volume 8, Issue 1, Pages 308-318Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg700803k
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Salts of bis[[1,1'-biphenyl]-2,2'-diolato-O,O'] borate. (4) were prepared by the reaction of boric acid with 2,2'-dihydroxybiphenyl in the presence of various cations. Ten salts were crystallized, and their structures were solved by X-ray diffraction. In all cases examined, spiroborate 4 favors enantiomeric (R,R) and (SS) structures with a flattened D-2 geometry. Moreover, the crystals analyzed all incorporate the two enantiomers in a 1: 1 ratio, even when the cations themselves are chiral and enantiomerically pure. In crystals of certain salts (NH4+, NH2Me2+, NMe4+, PPh4+, and MBA(+)), the packing of spiroborate 4 can be considered to define homochiral layers; in other salts, however, the organization of the anions is helical (NMe4+), columnar (NPr4+), or can be described as either layered or columnar (NBu4+ and NPent(4)(+)). These variations presumably arise because neighboring anions are not positioned reliably by strong directional interactions between them. Derivatives of spiroborate 4 that can engage in such interactions are expected to have well-defined molecular geometries and to serve as effective subunits for engineering crystals and other ordered materials with predetermined structures and properties.
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