Theory of Anodic Stripping Square Wave Voltammetry on Spherical Mercury Electrodes

Relationships between dimensionless anodic stripping square-wave voltammetric net peak currents and the dimensionless inverse electrode radius are curves with two asymptotes that depend on the duration of accumulation. The theory applies to reversible reduction of amalgam forming ions on stationary macro and micro spherical and hemispherical mercury electrodes.