Journal
CORROSION SCIENCE
Volume 87, Issue -, Pages 479-488Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2014.07.016
Keywords
Ceramic; Tantalum oxide; SEM; XRD; Oxidation
Funding
- National Natural Science Foundation of China [51221001, 51272213]
- 111 project [08040]
- NPU Foundation for fundamental Research
- Research Fund of the State Key Laboratory of Solidification Processing (NWPU), China [85-TZ-2013]
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A TaxHf1-xB2-SiC coating was prepared by in-situ reaction method on SiC coated C/C composites. TaxHf1-xB2 phase is the form of solid solution between TaB2 and HfB2. Isothermal oxidation behavior at 1773 K and ablation behavior of the coated C/C were tested. TaxHf1-xB2-SiC/SiC coating could protect the C/C from oxidation at 1773 K for 1480 h and ablation above 2200 K for 40 s. During oxidation, oxides of Ta and Hf atoms exist as pinning phases in the compound glass layer consisted of outer Ta-Si-O compound silicate layer and inner SiO2 glass layer, which was responsible for the excellent oxidation resistance. (c) 2014 Elsevier Ltd. All rights reserved.
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