The role of aluminum distribution on the local corrosion resistance of the microstructure in a sand-cast AM50 alloy

Site-specific analytical electron microscopy was performed on a corroded sand-cast AM50 alloy. Areas close to partially divorced eutectic were the regions with less corrosion damage. The corrosion product layer in these areas consisted of a columnar section of predominantly amorphous MgO. At the alloy interface, an aluminum-rich layer was identified. Electron energy-loss spectroscopy suggests this layer is metallic in character. The corrosion product film on the primary alpha-Mg grains possessed a bi-layer morphology: a thin columnar film and a thicker, porous sub-layer. The formation of the Al-rich layer depends on the Al content in solid solution at a specific location. (C) 2013 Elsevier Ltd. All rights reserved.