4.7 Article

A comprehensive study on crude methanolic extract of Artemisia pallens (Asteraceae) and its active component as effective corrosion inhibitors of mild steel in acid solution

Journal

CORROSION SCIENCE
Volume 60, Issue -, Pages 193-204

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2012.03.036

Keywords

Mild steel; Weight loss; Raman spectroscopy; XPS; IR spectroscopy; Acid inhibition

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Corrosion inhibition effects of crude methanolic extract of Artemisia pallens on mild steel in 1 mol l(-1) HCl were studied by weight loss and electrochemical technique. Arbutin. an active principle from A. pallens and the crude methanolic extract exhibited inhibition efficiency of 93% and 98% in 400 mg l(-1) concentration at 30 degrees C respectively. The results indicated that arbutin in acidic medium acted as good anti-corrosive agent synergistically with its hydrolyzed products hydroquinone and D-glucose. Adsorption of both the inhibitors on mild steel surface conformed to the Langmuir isotherm with standard adsorption free energy of -33.07 kJ mol(-1) for arbutin. (c) 2012 Elsevier Ltd. All rights reserved.

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