Journal
CORROSION SCIENCE
Volume 50, Issue 12, Pages 3455-3466Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2008.09.015
Keywords
Aluminium; X-ray microtomography; Acid corrosion; Exfoliation corrosion
Funding
- Alcan Technology Fund
- US Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
- Engineering and Physical Sciences Research Council [EP/D50029X/1] Funding Source: researchfish
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Susceptibility to localized corrosion of AlMgSi (AA6016 and AA6111) alloys in certain aggressive environments is high. In this study, synchrotron X-ray microtomography was used to monitor non-destructively corrosion processes within bulk materials. In the selected aggressive solutions, surface-deformed layers showed high localized corrosion susceptibility, but are more stable than the bulk of the alloy during corrosion propagation. In addition, exfoliation-like attack was observed as a transition from intergranular attack. This directed corrosion is not related to grain or crystallographic structure. Finally, intermetallic particles dissolution inside the materials after contact with aggressive solution of the intergranular corrosion path was evidenced. (C) 2008 Elsevier Ltd. All rights reserved.
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