Journal
CORROSION ENGINEERING SCIENCE AND TECHNOLOGY
Volume 45, Issue 2, Pages 115-135Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1179/174327808X286437
Keywords
Ferrous iron carbonite; Siderite; Standard state properties; Equilibrium constant; Solubility; Carbon dioxide corrosion film
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An extensive review of entropy, enthalpy of formation and Gibbs energy of formation, heat capacity, aqueous solubility and solubility constant of FeCO3 is given. A consistent set of thermodynamic properties for FeCO3 and relevant aqueous species is selected and recommended for use. Speciation schemes for aqueous FeCO3 are reviewed and evaluated. Issues related to supersaturation of FeCO3 are discussed. Works on the thermal decomposition of FeCO3 are presented and an overview of measured solubility and synthesis of FeCO3 is given.
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