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Lewis acidity of boron compounds

Journal

COORDINATION CHEMISTRY REVIEWS
Volume 270, Issue -, Pages 75-88

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2013.10.017

Keywords

Boron; Lewis acidity; Structure-property relationships; Acidity scale

Funding

  1. Russian Foundation for Basic Research [12-03-00772, 13-03-00581]

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The effects of different electronic and structural factors in determining the Lewis acidity of boron compounds are analyzed. Scales of Lewis acidity for boron Lewis acids based on the Gutmann-Beckett and Childs methods have been constructed using data available in the literature. The Lewis acidities of transient boron Lewis acids have been estimated and their high Lewis acidity has been confirmed. (c) 2013 Elsevier B.V. All rights reserved.

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