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Oxoanion systems containing trivalent actinides

Journal

COORDINATION CHEMISTRY REVIEWS
Volume 266, Issue -, Pages 16-27

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2013.07.009

Keywords

Actinide oxoanion compounds; Actinide iodate; Actinide borate; Actinide phosphite; Lanthanide oxoanion compounds

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A review of trivalent actinide oxoanion compounds is presented. This work focuses on the systematics and periodic trends in the trivalent actinide series from Pu(III) to Cf(III). Three systems, are focused on: iodates, phosphites, and borates. In the first two series, the structure and bonding parallels that of lanthanides; whereas in the final series the chemistry of the actinides is distinct from the lanthanides. (C) 2013 Elsevier B.V. All rights reserved.

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