4.8 Review

Chemistry of rhenium carbyne complexes

Journal

COORDINATION CHEMISTRY REVIEWS
Volume 257, Issue 3-4, Pages 666-701

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2012.08.005

Keywords

Rhenium; Carbyne; Alkylidyne; Metal-carbon multiple bond; Carbene

Funding

  1. Hong Kong Research Grant Council
  2. Hong Kong University of Science and Technology

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There has been much interest in the chemistry of rhenium carbyne complexes, complexes with a rhenium carbon triple bond. A number of rhenium carbyne complexes have been obtained from various synthetic routes. A variety of interesting chemical properties of rhenium carbyne complexes have also been reported. This review summarizes the work related to the synthesis and reactivity of mononuclear rhenium carbyne complexes. (C) 2012 Elsevier B.V. All rights reserved.

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