Journal
COORDINATION CHEMISTRY REVIEWS
Volume 256, Issue 13-14, Pages 1418-1434Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2012.04.005
Keywords
Active sites; Asymmetric; Epoxidation; Hydrocarbons; Hydrogen peroxide; Iron; Manganese; Non-heme; Oxidation; Mechanism
Categories
Funding
- Russian Foundation for Basic Research [12-03-00782]
Ask authors/readers for more resources
The discovery of simple and efficient catalyst systems for the selective oxofunctionalization of hydrocarbons is a challenging task of modern chemistry. The biomimetic approach, which aims at mimicking the reactivity of natural enzymes in catalyzed transformation with synthetic low-molecular weight compounds, has been widely applied to the search for new transition metal based catalyst systems in the last two decades. In effect, numerous iron and manganese complexes modeling the catalytic performance of non-heme metal-containing monooxygenases have been reported and intensively investigated. In this contribution, non-heme iron- and manganese catalyzed selective oxidations of alkanes, as well as chemo-and stereoselective epoxidations and cis-dihydroxylations of alkenes, using H2O2 as the oxygen source, are reviewed, with major focus on the their synthetic potential. Recent experimental investigations of the nature of catalytically active species and mechanisms of their action are summarized. (C) 2012 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available