Journal
COORDINATION CHEMISTRY REVIEWS
Volume 256, Issue 23-24, Pages 2893-2920Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2012.05.027
Keywords
Poly(ethylene glycol); PEG; Catalysis; Organometallic chemistry; Transition metals; Post-transition metals; Palladium; Copper; Lewis acids; Nanoparticles; Microwaves; Cross-coupling; Heterocycles; Recycling
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Funding
- CNRS
- MENRT
- French Embassy in Moscow
- Russian Foundation of Basic Research [08-03-92505]
- bilteral programme GDRI Homogeneous catalysis for sustainable development
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Poly(ethylene glycol)s (PEGs) are an interesting environment-friendly alternative to classical solvents. Their combination with metals and metallic salts provides powerful reaction systems for a wide variety of transformations. This study presents an overview of the various reactions developed in PEG together with a metallic species. The influence of PEG on the reaction course, the stabilizing effects of the polymer on the metals and the recycling possibility are reported for the various metallic elements of the periodic table.
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