Journal
COORDINATION CHEMISTRY REVIEWS
Volume 256, Issue 11-12, Pages 938-952Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2012.01.002
Keywords
[3+2] cycloadditions; 1,3-Dipolar cycloaddition reactions; Asymmetric cycloadditions; Asymmetric catalysis; Organocatalysts
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Funding
- National 973 Program Foundation [2010CB732202]
- Natural Science Foundation of China [21172227]
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This review focuses on recent progress in organocatalytic and metal-mediated asymmetric [3 + 2] cycloadditions, including 'click' chemistry, asymmetric 1,3-dipolar and asymmetric non-1,3-dipolar [3 + 2] cycloadditions. The theoretical aspects and synthetic applications of these organocatalytic and metal-mediated asymmetric [3 + 2] cycloadditions are summarized. In addition, an understanding of the mechanistic details which lead to efficient stereoselectivity in organocatalytic and metal-mediated asymmetric [3 + 2] cycloadditions is provided. Most of the references reviewed in this paper are from 2007 upto now. (C) 2012 Elsevier B.V. All rights reserved.
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