Journal
COORDINATION CHEMISTRY REVIEWS
Volume 255, Issue 7-8, Pages 920-937Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2011.01.009
Keywords
Atom and group transfer; Metal-to-ligand multiple bond; Oxos; Imides; Nitrides
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Funding
- NIH [GM-070757]
- NSF [CHE-0132216, 0750234]
- Dreyfus Foundation
- Alfred P. Sloan Foundation
- NSF Graduate Fellowship
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0750234] Funding Source: National Science Foundation
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Mid-to-late transition metal complexes that feature terminal, multiply bonded ligands such as oxos, imides, and nitrides have been invoked as intermediates in several catalytic transformations of synthetic and biological significance. Until about ten years ago, isolable examples of such species were virtually unknown. Over the past decade or so, numerous chemically well-defined examples of such species have been discovered. In this context, the present review summarizes the development of 4- and 5-coordinate Fe(E) and Co(E) species under local three-fold symmetry. (C) 2011 Elsevier By. All rights reserved.
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