Journal
COORDINATION CHEMISTRY REVIEWS
Volume 255, Issue 15-16, Pages 1733-1790Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2011.02.001
Keywords
Cyclopentadiene derivatives; Pentaphenylcyclopentadiene; Decaphenylmetallocenes; Sandwich compounds; Penta-arylcyclopentadienyl compounds; Penta-arylcyclopentadiene
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This review covers the coordination and general chemistry of the 1,2,3,4,5-penta-arylcyclopentadiene system, as anion, C5Ar5-, radical, C5Ar5 center dot, and cation, C5Ar5+, as well as the neutral diene, C5Ar5H, and its derivatives. The structural rigidity and steric saturation offered by the penta-arylcyclopentadienyl ligand give rise to definite structural and geometric properties in its complexes that distinguish its chemistry from that of the parent cyclopentadiene. (C) 2011 Elsevier B.V. All rights reserved.
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