Journal
COORDINATION CHEMISTRY REVIEWS
Volume 255, Issue 11-12, Pages 1319-1341Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2010.11.019
Keywords
Silicon; Germanium; Halides; X-ray structures
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Funding
- EPSRC [EP/H007369/1, EP/C006763/1]
- EPSRC [EP/H007369/1, EP/I033394/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/C006763/1, EP/I033394/1, EP/H007369/1] Funding Source: researchfish
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The coordination chemistry of silicon(IV) and (II) and germanium(IV) and (II) halides with neutral donor ligands from groups 15 (N, P or As) and 16(O, S or Se) is reviewed: N-heterocyclic carbene complexes are also included. The focus is mainly on results published after 1990 and illustrates that significant recent developments have been made in the coordination chemistry of low-valent silicon and germanium halide complexes in particular; this is expected to pave the way for much new reaction chemistry both from a fundamental and application-driven perspective. (C) 2010 Elsevier B.V. All rights reserved.
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