Journal
COORDINATION CHEMISTRY REVIEWS
Volume 255, Issue 19-20, Pages 2371-2377Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2011.01.055
Keywords
(Arylimido)vanadium(V); Self-assembling; Alkoxido bridging; Imido bridging; CH-pi interaction; Highly ordered molecular arrangement
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Funding
- Grants-in-Aid for Scientific Research [22655028, 22108516] Funding Source: KAKEN
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(Imido)vanadium(V) complexes have attracted much attention because of their potential applications as catalysts. Compared with oxo ligands, imido ligands can possess a substituent on the imido nitrogen so that the steric and electronic characters of the metal center are considered to be controlled by the properties of the nitrogen substituent. In such a sense, the design of the imido ligands is envisioned to be one of the key factors in the development of efficient catalysts. Furthermore, architectural control of transition metal-directed assembly to create organized nanostructures is of importance for advanced materials. This review highlights self-assembling properties of (arylimido)vanadium(V) compounds. (C) 2011 Elsevier B.V. All rights reserved.
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